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https://repositorio.ufrn.br/handle/1/3052| Title: | Synthesis and characterization of hybrids derived from vermiculite chloropropyl and aliphatic diamines |
| Authors: | Alves, Ana Paula de Melo Silva, André Leonardo P. Silva, Oberto G. da Fonseca, Maria G. da Arakaki, Luiza N. H. Espínola, J. G. P. |
| Keywords: | Clay;Inorganic–Organic hybrids;Vermiculite |
| Issue Date: | 2007 |
| Publisher: | Journal of Thermal Analysis and Calorimetry |
| Citation: | ALVES, Ana Paula M.; SILVA, André Leonardo P.; SILVA, Oberto G. da; FONSECA, Maria G. da; ARAKAKI, Luiza N. H. ; ESPÍNOLA, J. G. P. (2007) |
| Abstract: | Silylation of vermiculite surface with organosilane (H3CO)3SiR, being R is the corresponding organic moieties –CH2CH2CH2Cl, were carried out to yield organofunctionalized nanomaterial, named as VCl. The product reacted subsequently with three aliphatic diamines H2N (CH2)nNH2 (n=2, 4 and 6). The new hybrids were characterized by elemental analysis, infrared pectroscopy, X-ray diffraction and thermogravimetry. The grafting chloro derivates onto surface amounted to 2.1 mmol g –1. The incorporation of alkyl amines was more effective for butyl>ethylene>hexyldiamines. The sequence is in agreement with thermogravimetry and elemental analysis data |
| Description: | ALVES, Ana Paula de Melo et al. Synthesis and characterization of hybrids derived from vermiculite chloropropyl and aliphatic diamines. Journal of Thermal Analysis and Calorimetry, v.87, n. 3, p.771–774, 2007. |
| URI: | https://repositorio.ufrn.br/jspui/handle/1/3052 |
| Appears in Collections: | IQ - Artigos publicados em periódicos |
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